There is no built-in heating system in my Australian-standard un-insulated apartment, and the plug-in electric radiators do not have enough power to raise the temperature by a degree. In the past two winters, I used the gas stove as a heater. It is generally unwise to heat an enclosed space without purpose-built ventilation (such as a chimney) by burning something, because of the risk of CO poisoning. Even before CO becomes a problem, suffocation may occur because the CO2 concentration rises and oxygen concentration falls. Therefore, before deciding to heat with a gas stove, I looked up the research, made thorough calculations and checked them several times. I also bought a CO detector, tested it and placed it next to the gas stove. The ceiling has a smoke alarm permanently attached, but this only detects soot in the air, not gases like CO.
For the calculations, I looked up how much heat is produced by burning a cubic metre or kilogram of CH4 (natural gas), how much the temperature of the air in the apartment should rise as a result, how much CO2 the burning produces, and what the safe limits of long-term CO2 exposure are.
The energy content of CH4 is 37.2 MJ/m3, equivalently 50-55.5 MJ/kg. A pilot light of a water heater is estimated to produce 5.3 kWh/day = 20 MJ/day of heat, but a gas stove’s biggest burner turned fully on is estimated to produce 5-15 MJ/h, depending on the stove and the data source.
The chemical reaction of burning natural gas when oxygen is not a limiting factor is CH4 +2*O2 =CO2 +2*H2O. The molar masses of these gases are CH4=16 g/mol, O2=32 g/mol, CO2=44 g/mol, H2O=18 g/mol, air 29 g/mol. One stove burner on full for 1 hour uses about 0.182 kg =0.255 m3 of CH4 and 0.364 kg of O2, which depletes 1.82 kg = 1.52 m3 of air. The burning produces 2.75*0.182 = 0.5 kg = 0.41 m3 of CO2. The CO2 is denser than air, which is why it may remain in the apartment and displace air when the cracks around the windows are relatively high up. On the other hand, the CO2 also mixes with the air, so may escape at the same rate. Or alternatively, the CO2 is hot, so may rise and escape faster than air. For safety calculations, I want to use a conservative estimate, so assume that the CO2 remains in the apartment.
The volume of the apartment is 6x5x2.5 m =75 m^3. The density of air at room temperature is 1.2 kg/m^3, thus the mass of air in the apartment is 90 kg. The specific heat of air is 1005 kJ/(kg*K) at 20C. The walls and ceiling leak heat, thus more energy is actually needed to heat the apartment by a given amount than the calculation using only air shows. It takes 900 kJ of heat to raise the temperature of the air, not the walls, by 10C (from 12C to 22C). This requires 9/555 kg = 9/(16*555) kmol of CH4 with estimated energy density 55500 kJ/kg. Burning that CH4 also takes 9/(8*555) kmol of O2 and produces 9*11/(4*555) kmol = 9/200 kg of CO2.
The normal concentration of CO2 in outside air is 350-450 ppm. Estimate the baseline concentration in inside air to be 1/2000 ppm because of breathing and poor ventilation. Adding 1/2000 ppm from heating, the CO2 concentration reaches 1/1000 ppm. This is below the legal limit for long-term exposure.
CO is produced in low-oxygen burning. As long as the CO2 concentration in the air is low and the oxygen concentration high, the risk of CO poisoning is small.
For the actual heating, I first tested running the smallest burner all day while I was at home, and paid attention to whether I felt sleepy and whether the air in the apartment smelled more stale than outside or in the corridor. There seemed to be no problems. For nighttime heating, I started with the smallest burner in the lowest setting, similarly paying attention to whether the air in the morning smelled staler than usual and whether I felt any different. Because there were no problems, I gradually increased the heating from week to week. The maximum I reached was to turn on the largest burner to less than half power, and one or two smaller burners fully. Together, these burners produced much less heat than the largest burner on full, as could be easily checked by feel when standing next to the stove. At night, the stove prevented the temperature in the apartment from dropping by the usual 2C, but did not increase it. The CO2 produced was probably far less than the bound I calculated above by assuming a 10C increase in temperature. Empirically, I’m still alive after two winters of letting the gas stove run overnight.
Help me to choose gas service for home and office..